| Basic Stats | Extended Stats |
| Wins | ||||||||||||||||||
| Player | Pos | Team | GP | GS | IP | W | L | SV | SVO | H | R | HR | ER | ERA | BB | K | TP | WHIP |
| Bronson Arroyo | SP | CIN | 1 | 1 | 7.0 | 1 | 0 | 0 | 0 | 1 | 0 | 0 | 0 | 0.00 | 1 | 4 | 91 | 0.29 |
| Madison Bumgarner | SP | SF | 3 | 3 | 15.0 | 1 | 2 | 0 | 0 | 17 | 10 | 3 | 10 | 6.00 | 4 | 14 | 231 | 1.40 |
| Matt Cain | SP | SF | 5 | 5 | 30.0 | 2 | 2 | 0 | 0 | 27 | 12 | 6 | 12 | 3.60 | 7 | 20 | 475 | 1.13 |
| Chris Carpenter | SP | STL | 3 | 3 | 13.2 | 1 | 2 | 0 | 0 | 19 | 10 | 1 | 4 | 2.63 | 6 | 9 | 258 | 1.83 |
| Santiago Casilla | RP | SF | 11 | 0 | 7.0 | 1 | 0 | 0 | 0 | 8 | 2 | 0 | 1 | 1.29 | 1 | 8 | 150 | 1.29 |
| Sam LeCure | RP | CIN | 3 | 0 | 4.0 | 1 | 0 | 0 | 0 | 2 | 0 | 0 | 0 | 0.00 | 2 | 5 | 53 | 1.00 |
| Tim Lincecum | SP | SF | 6 | 1 | 17.2 | 1 | 1 | 0 | 0 | 9 | 5 | 0 | 5 | 2.55 | 5 | 20 | 259 | 0.79 |
| Kyle Lohse | SP | STL | 4 | 4 | 20.1 | 2 | 1 | 0 | 0 | 21 | 9 | 2 | 9 | 3.98 | 8 | 14 | 322 | 1.43 |
| Lance Lynn | SP | STL | 6 | 2 | 11.0 | 1 | 2 | 0 | 0 | 13 | 11 | 3 | 7 | 5.73 | 6 | 15 | 226 | 1.73 |
| Ryan Mattheus | RP | WAS | 3 | 0 | 3.0 | 1 | 0 | 0 | 0 | 3 | 2 | 0 | 2 | 6.00 | 1 | 0 | 42 | 1.33 |
| Jason Motte | RP | STL | 6 | 0 | 8.1 | 1 | 0 | 3 | 3 | 7 | 2 | 1 | 2 | 2.16 | 1 | 2 | 123 | 0.96 |
| Edward Mujica | RP | STL | 9 | 0 | 7.2 | 1 | 0 | 0 | 0 | 9 | 2 | 0 | 2 | 2.35 | 1 | 4 | 99 | 1.30 |
| Sergio Romo | RP | SF | 10 | 0 | 10.2 | 1 | 0 | 4 | 4 | 4 | 1 | 0 | 1 | 0.84 | 1 | 9 | 151 | 0.47 |
| Drew Storen | RP | WAS | 4 | 0 | 4.0 | 1 | 1 | 1 | 2 | 3 | 4 | 0 | 4 | 9.00 | 3 | 6 | 80 | 1.50 |
| Ryan Vogelsong | SP | SF | 4 | 4 | 24.2 | 3 | 0 | 0 | 0 | 16 | 3 | 0 | 3 | 1.09 | 10 | 21 | 407 | 1.05 |
| Adam Wainwright | SP | STL | 3 | 3 | 15.0 | 1 | 0 | 0 | 0 | 17 | 8 | 4 | 8 | 4.80 | 3 | 20 | 249 | 1.33 |
| Barry Zito | SP | SF | 3 | 3 | 16.0 | 2 | 0 | 0 | 0 | 16 | 3 | 1 | 3 | 1.69 | 6 | 13 | 272 | 1.38 |
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