| 2012 Results | |||
| Australian Open | |||
| Rd | Opponent | W/L | Score |
| 1 | Gisela Dulko | W | 6-0, 6-1 |
| 2 | Jamie Hampton | W | 6-0, 6-1 |
| 3 | Angelique Kerber | W | 6-1, 6-2 |
| 4 | Sabine Lisicki | W | 3-6, 6-2, 6-3 |
| QF | Ekaterina Makarova | W | 6-2, 6-3 |
| SF | Petra Kvitova | W | 6-2, 3-6, 6-4 |
| F | Victoria Azarenka | L | 3-6, 0-6 |
| Open GDF SUEZ | |||
| Rd | Opponent | W/L | Score |
| 2 | Chanelle Scheepers | W | 6-3, 6-1 |
| QF | Angelique Kerber | L | 4-6, 4-6 |
| BNP Paribas Open | |||
| Rd | Opponent | W/L | Score |
| F | Victoria Azarenka | L | 2-6, 3-6 |
| Sony Ericsson Open | |||
| Rd | Opponent | W/L | Score |
| 2 | Shahar Peer | W | 4-6, 6-3, 6-3 |
| 3 | Sloane Stephens | W | 6-4, 6-2 |
| 4 | Ekaterina Makarova | W | 6-4, 7-6(7-3) |
| QF | Li Na | W | 6-3, 6-0 |
| SF | Caroline Wozniacki | W | 4-6, 6-2, 6-4 |
| F | Agnieszka Radwanska | L | 5-7, 4-6 |
| Porsche Tennis Grand Prix | |||
| Rd | Opponent | W/L | Score |
| 2 | Alize Cornet | W | 6-3, 1-0, retired |
| QF | Samantha Stosur | W | 6-7(5-7), 7-6(7-5), 7-5 |
| SF | Petra Kvitova | W | 6-4, 7-6(7-3) |
| F | Victoria Azarenka | W | 6-1, 6-4 |
| Mutua Madrid Open | |||
| Rd | Opponent | W/L | Score |
| 1 | Irina Begu | W | 6-0, 6-3 |
| 2 | Klara Zakopalova | W | 6-4, 6-3 |
| 3 | Lucie Safarova | W | , retired |
| QF | Serena Williams | L | 1-6, 3-6 |
| Internazionali BNL d'Italia | |||
| Rd | Opponent | W/L | Score |
| 2 | Christina McHale | W | 7-5, 7-5 |
| 3 | Ana Ivanovic | W | 7-6(7-4), 6-3 |
| QF | Venus Williams | W | 6-4, 6-3 |
| SF | Angelique Kerber | W | 6-3, 6-4 |
| F | Li Na | W | 4-6, 6-4, 7-6(7-5) |
| French Open | |||
| Rd | Opponent | W/L | Score |
| 1 | Alexandra Cadantu | W | 6-0, 6-0 |
| 2 | Ayumi Morita | W | 6-1, 6-1 |
| 3 | Peng Shuai | W | 6-2, 6-1 |
| 4 | Klara Zakopalova | W | 6-4, 6-7(5-7), 6-2 |
| QF | Kaia Kanepi | W | 6-2, 6-3 |
| SF | Petra Kvitova | W | 6-3, 6-3 |
| F | Sara Errani | W | 6-3, 6-2 |
| Wimbledon | |||
| Rd | Opponent | W/L | Score |
| 1 | Anastassia Rodionova | W | 6-2, 6-3 |
| 2 | Tszvetana Pironkova | W | 7-6(7-3), 6-7(3-7), 6-0 |
| 3 | Su-Wei Hsieh | W | 6-1, 6-4 |
| 4 | Sabine Lisicki | L | 4-6, 3-6 |
| US Open | |||
| Rd | Opponent | W/L | Score |
| 1 | Melinda Czink | W | 6-2, 6-2 |
| 2 | Lourdes Dominguez Lino | W | 6-0, 6-1 |
| 3 | Mallory Burdette | W | 6-1, 6-1 |
| 4 | Nadia Petrova | W | 6-1, 4-6, 6-4 |
| QF | Marion Bartoli | W | 3-6, 6-3, 6-4 |
| SF | Victoria Azarenka | L | 6-3, 2-6, 4-6 |
| Toray Pan Pacific Open | |||
| Rd | Opponent | W/L | Score |
| 2 | Heather Watson | W | 6-7(7-9), 6-3, 6-4 |
| 3 | Lucie Safarova | W | 6-2, 7-6(7-5) |
| QF | Samantha Stosur | L | 4-6, 6(10)-7(12) |
| China Open | |||
| Rd | Opponent | W/L | Score |
| 1 | Simona Halep | W | 7-5, 7-5 |
| 2 | Sorana Cirstea | W | 6-2, 6-2 |
| 3 | Polona Hercog | W | 6-0, 6-2 |
| QF | Angelique Kerber | W | 6-0, 3-0, retired |
| SF | Li Na | W | 6-4, 6-0 |
| F | Victoria Azarenka | L | 3-6, 1-6 |
| TEB BNP PARIBAS WTA Championships | |||
| Rd | Opponent | W/L | Score |
| 0 | Sara Errani | W | 6-3, 6-2 |
| SF | Victoria Azarenka | W | 6-4, 6-2 |
| F | Serena Williams | L | 4-6, 3-6 |
