| 2013 Results | |||
| Australian Open | |||
| Rd | Opponent | W/L | Score |
| 1 | Olga Puchkova | W | 6-0, 6-0 |
| 2 | Misaki Doi | W | 6-0, 6-0 |
| 3 | Venus Williams | W | 6-1, 6-3 |
| 4 | Kirsten Flipkens | W | 6-1, 6-0 |
| QF | Ekaterina Makarova | W | 6-2, 6-2 |
| SF | Li Na | L | 2-6, 2-6 |
| Qatar Open | |||
| Rd | Opponent | W/L | Score |
| 2 | Caroline Garcia | W | 6-3, 6-2 |
| 3 | Klara Zakopalova | W | 6-3, 6-3 |
| QF | Samantha Stosur | W | 6-2, 6-4 |
| SF | Serena Williams | L | 3-6, 2-6 |
| BNP Paribas Open | |||
| Rd | Opponent | W/L | Score |
| 2 | Francesca Schiavone | W | 6-2, 6-1 |
| 3 | Carla Suarez Navarro | W | 7-5, 6-3 |
| 4 | Lara Arruabarrena-Vecino | W | 7-5, 6-0 |
| F | Caroline Wozniacki | W | 6-2, 6-2 |
| Miami Masters | |||
| Rd | Opponent | W/L | Score |
| QF | Sara Errani | ||
| SF | Jelena Jankovic | ||
| F | Serena Williams | ||
| Porsche Tennis Grand Prix | |||
| Rd | Opponent | W/L | Score |
| 2 | Lucie Safarova | W | 6-4, 6-7(3-7), 6-3 |
| QF | Ana Ivanovic | W | 7-5, 4-6, 6-4 |
| SF | Angelique Kerber | W | 6-3, 2-6, 7-5 |
| F | Li Na | W | 6-4, 6-3 |
| Tennis Masters Madrid | |||
| Rd | Opponent | W/L | Score |
| 1 | Alexandra Dulgheru | W | 7-5, 6-2 |
| 2 | Christina McHale | W | 6-1, 6-2 |
| 3 | Sabine Lisicki | W | 6-2, 7-5 |
| QF | Kaia Kanepi | W | 6-2, 6-4 |
| SF | Ana Ivanovic | W | 6-4, 6-3 |
| F | Serena Williams | L | 1-6, 4-6 |
| Internazionali BNL d'Italia | |||
| Rd | Opponent | W/L | Score |
| 2 | Garbine Muguruza | W | 6-2, 6-2 |
| 3 | Sloane Stephens | W | 6-2, 6-1 |
| QF | Sara Errani | L | , retired |
| Roland Garros | |||
| Rd | Opponent | W/L | Score |
| 1 | Su-Wei Hsieh | W | 6-2, 6-1 |
| 2 | Eugenie Bouchard | W | 6-2, 6-4 |
| 3 | Jie Zheng | W | 6-1, 7-5 |
| 4 | Sloane Stephens | W | 6-4, 6-3 |
| QF | Jelena Jankovic | W | 0-6, 6-4, 6-3 |
| SF | Victoria Azarenka | W | 6-1, 2-6, 6-4 |
| F | Serena Williams | L | 4-6, 4-6 |
